def add Segovia and visit the Alcazar, cathedral and aqueduct with a nice lunch at the plaza mayor.
palacio Real ,do it,and have lunch in its cafeteria.
templo de Debod is nice at parque del oeste,one of all time favorite places when i used to live in Madrid. you might consider taken the Teleferico ,cable car to casa de campo,many attractions there zoo,aquarium,attraction ride park; even just to take the cable car and go over bridge of segovia, very nice.
El Escorial and Valle de los Caidos is nice, too.
the Retiro park, for a boat ride in the lake and ice cream with horchata drink ::)
you have a nice trip going ,enjoy it.