Try using
www.viamichelin.com. All you have to do is set your itinerary and you will get maps, details of when do u have to take ur next turn, toll costs, etc. I used it last year on a trip all the way to Croatia from Madrid last summer and it worked pretty well. You can even set as starting point one street of Madrid and a street of Moscow as ending point, and you will get not only which highways to take, but also the best route inside both cities to get to your final destination.