I get the idea you might be looking for things like "turismo rural".
An example would be
http://www.charoshouses.com/ which is in the "charming places" category and very typical. Not a Grand Villa, which would be more city-oriented, but one of many hundreds of wonderful, dreamy, places to stay - - pretty much anywhere in Spain.
The main association that deals with these sorts spots is called ASETUR and found at:
http://www.ecoturismorural.com/Asetur1Uk.asp