Jan,
There appears to be a blog all about that zone.
http://smbenquerencia.blogspot.com/If it is the one I think it is then it is not a particuarly great neighbourhood, and is dominated by the industrial park there (which smells a bit).
But, in Spain there seems to be bars and cafeterias for breakfast on every street corner. And given the closeness of the poligono, there will be plenty. I wouldn't worry about it, you'll get your toast with tomato
:-)
p.s. In front of the station in Toledo are plenty of bars and restaurants.