This is our current alphabet:
a,b,c,d,e,f,g,h,i,j,k,l,ll,m,n,ñ,o,p,q,r,s,t,u,v,w,x,y,z
The letter ch was "abolished" some years ago. We still have two differences with english alphabet: "ll" and "ñ".
Other letters, as k and w are rarely used. Only a few words in spanish have them (and they are usually of foreign origin).
The "r" and the "rr" are the same letter, but different phonema (is that the word?), that is, they are pronounced differently. A "r" is converted into a "rr" when, as Deibid sayed, it is between two vowels. Every word starting with a "r" is pronounced the same way as if it had an "rr" (example: rosa, perro).
As for adverbs ending in "-mente" are almost exactly the same than adverbs in english ending in -ly (quickly <=> rápidamente, calmly <=> calmadamente, perfectly <=> perfectamente).
Spanish words are usually made plural by adding a "-s" or a "-es" at the end. Example: perro => perros, persona => personas, español => españoles.
Fernando